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71.
72.
In this work, the benefits of high-frequency (HF) radar currents for oil spill modeling and trajectory analysis of floating objects are analyzed. The HF radar performance is evaluated by means of comparison between a drifter buoy trajectory and the one simulated using a Lagrangian trajectory model. A methodology to optimize the transport model performance and to calculate the search area of the predicted positions is proposed. This method is applied to data collected during the Galicia HF Radar Experience. This experiment was carried out to explore the capabilities of this technology for operational monitoring along the Spanish coast. Two long-range HF radar stations were installed and operated between November 2005 and February 2006 on the Galician coast. In addition, a drifter buoy was released inside the coverage area of the radar. The HF radar currents, as well as numerical wind data were used to simulate the buoy trajectory using the TESEO oil spill transport model. In order to evaluate the contribution of HF radar currents to trajectory analysis, two simulation alternatives were carried out. In the first one, wind data were used to simulate the motion of the buoy. In the second alternative, surface currents from the HF radar were also taken into account. For each alternative, the model was calibrated by means of the global optimization algorithm SCEM-UA (Shuffled Complex Evolution Metropolis) in order to obtain the probability density function of the model parameters. The buoy trajectory was computed for 24 h intervals using a Monte Carlo approach based on the results provided in the calibration process. A bivariate kernel estimator was applied to determine the 95% confidence areas. The analysis performed showed that simulated trajectories integrating HF radar currents are more accurate than those obtained considering only wind numerical data. After a 24 h period, the error in the final simulated position improves using HF radar currents. Averaging the information from all the simulated daily periods, the mean search and rescue area calculated using HF radar currents, is reduced by approximately a 62% in comparison with the search area calculated without these data. These results show the positive contribution of HF radar currents for trajectory analysis, and demonstrate that these data combined with atmospheric forecast models, are of value for trajectory analysis of oil spills or floating objects.  相似文献   
73.
Juvenile Senegalese soles were exposed through 28-day laboratory and field (in situ) bioassays to sediments from three sites of the Sado estuary (W Portugal): a reference and two contaminated by metallic and organic contaminants. Fish were surveyed for ten hepatic histopathological alterations divided by four distinct reaction patterns and integrated through the estimation of individual histopathological condition indices. Fish exposed to contaminated sediments sustained more damage, with especial respect to regressive changes like necrosis. However, differences were observed between laboratory- and field-exposed animals, with the latest, for instance, exhibiting more pronounced fatty degeneration and hepatocellular eosinophilic alteration. Also, some lesions in fish exposed to the reference sediment indicate that in both assays unaccounted variables produced experimental background noise, such as hyaline degeneration in laboratory-exposed fish. Still, the field assays yielded results that were found to better reflect the overall levels of contaminants and physico-chemical characteristics of the tested sediments.  相似文献   
74.
Whilst the potential impact on beach users from microorganisms in water has received considerable attention, there has been relatively little investigation into microbial contaminants in sand. Thirty three beaches across Portugal were analyzed during a five year period (2006-2010) to determine the presence of yeasts, pathogenic fungi, dermatophytes, total coliforms, Escherichia coli and intestinal enterococci in sand.Our results showed that 60.4% of the samples were positive for fungi and that 25.2% were positive for the bacterial parameters. The most frequent fungal species found were Candida sp. and Aspergillus sp., whereas intestinal enterococci were the most frequently isolated bacteria. Positive associations were detected among analyzed parameters and country-regions but none among those parameters and sampling period.Regarding threshold values, we propose 15 cfu/g for yeasts, 17 cfu/g for potential pathogenic fungi, 8 cfu/g for dermatophytes. Eighty four cfu/g for coliforms, 250 cfu/g for E. coli, and 100 cfu/g for intestinal enterococci.  相似文献   
75.
Elemental and isotopic compositions of organic matter in surficial sediments from five transects across Lagoa do Caçó (Brazil) were analyzed to identify the depth-related processes that affect the production and deposition of sedimentary organic matter in this shallow tropical lake. Each of four transverse transects began at a margin dominated by aquatic macrophytes (Eleocharis), crossed the central deep part of the lake, and terminated in the opposite, macrophyte-dominated margin. In each transect, TOC concentrations, C/N ratios, and δ13C values decreased between 0 and 4 m, whereas δ15N values increased. The variables remained stable in sediment from 4 m water depth to the center of the lake at 10 m. The depth-related patterns reflect differences in both the delivery and the deposition of organic matter in the lake. Organic matter is produced in abundance in the marginal area by emersed and submerged macrophyte vegetation that diminishes with depth and disappears at 4 meters. After the disappearance of macrophytes, organic matter is produced at low rates principally by open-lake phytoplankton. Drawdown of dissolved oxygen is high in the lake margins, but it is low in the oligotrophic open waters of the lake. Preservation of organic matter is consequently better in sediments of the lake margins than in deep waters. The depth-related pattern of organic matter delivery and deposition in the sediments of Lagoa do Caçó, in which water levels are sensitive to groundwater fluctuations, shows that the elemental and isotopic compositions of sediment organic matter can provide a record of changes in the paleohydrology of this and other similar shallow lake systems.  相似文献   
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77.
The reactions of three structurally similar unsaturated alcohols, 2-buten-1-ol (crotyl alcohol), 2-methyl-2-propen-1-ol (MPO221) and 3-methyl-2-buten-1-ol (MBO321) with Cl atoms, have been investigated for the first time, using a 400 l Teflon reaction chamber coupled with gas chromatograph-coupled with flame-ionization detection (GC-FID). The experiments were performed at atmospheric pressure and at temperatures between 255 and 298 K, in air or nitrogen as the bath gas. The obtained kinetic data were used to derive the Arrhenius expressions , , (in units of cm3 molecule−1 s−1). Finally, atmospheric lifetimes of those unsaturated alcohols with respect to OH, NO3, O3 and Cl have been calculated.  相似文献   
78.
A detailed study was carried out on a piece of land that had been struck by lightning during the violent rainstorm that raged over the Island of S?o Miguel (Azores Archipelago) in late October 2006. Temperature and gas measurements (CO2, CO, H2S and CH4) were performed in four study trenches, dug in an area of ∼3 m2, where an underground fire had been initiated by the impact with a lightning stroke, followed by the emission of a column of gases and smoke. The soil under study was originally a well-pedogenized about 80 cm thick bed, made of volcanic clayey to silty tephra fallouts and contained 5.5–9.7% of organic matter. The underground fire was monitored for one week and revealed a peak release of 404 ppm CO and 3.4% CO2 originating from a horizon located about 45 cm under the soil surface. Measurements of temperature, performed one week after the impact, indicated a maximum value of 326°C inside the soil, while 516.5°C were measured on the surface of a lava block interred about 20 cm under the surface. Subsequently, a stratigraphic and sedimentologic study proved the role of the grain-size of the soil and of the organic matter content of the different horizons of the impact area, in determining the ratio between anoxic/oxidised combustion conditions and in the progress of the process itself. It was also noticed that combustion was not total all over in the soil bed and that the process had slightly migrated toward SW during the observation period. The combustion process went on for about ten days, in spite of several other violent rainstorms, until it was artificially extinguished through the excavations made to obtain study trenches. This particular circumstance evidenced the potential natural hazard represented by this kind of atmospheric event, especially in a land where the volcanic nature of the soil may easily mislead inexperienced observers and, consequently, delay proper action.  相似文献   
79.
Methodology for preliminary assessment of Natech risk in urban areas   总被引:1,自引:0,他引:1  
Concern for natural hazard-triggered technological disasters (Natech disasters) in densely populated and industrialized areas is growing. Residents living in urban areas subject to high natural hazard risk are often unaware of the potential for secondary disasters such as hazardous materials releases from neighboring industrial facilities, chemical storage warehouses or other establishments housing hazardous materials. Lessons from previous disasters, such as the Natech disaster during the Kocaeli earthquake in Turkey in 1999 call for the need to manage low frequency/high consequence events, particularly in today’s densely populated areas. However, there is little guidance available on how local governments and communities can assess Natech risk. To add to the problem, local governments often do not have the human or economic resources or expertise to carry out detailed risk assessments. In this article, we propose a methodology for preliminary assessment of Natech risk in urban areas. The proposed methodology is intended for use by local government officials in consultation with the public. The methodology considers possible interactions between the various systems in the urban environment: the physical infrastructure (e.g., industrial plants, lifeline systems, critical facilities), the community (e.g., population exposed), the natural environment (e.g., delicate ecosystems, river basins), and the risk and emergency management systems (e.g., structural and nonstructural measures). Factors related to vulnerability and hazard are analyzed and qualitative measures are recommended. Data from hazardous materials releases during the Kocaeli, Turkey earthquake of August 17, 1999 are used as a case study to demonstrate the applicability of the methodology. Limitations of the proposed methodology are discussed as well as future research needs.
Norio OkadaEmail:
  相似文献   
80.
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